Elimination of Methylene Blue by low-cost Biomaterial prepared from Local Natural Residue

  • Fatma LANSARI Department of hydrocarbons and renewable energie, University of Ahmed Draia Adrar, Algeria.
  • Meryem EDJEKOUANE Départment of hydrocarbons and renewable energies, University of Ahmed Draia Adrar, Algeria
  • Omar KHELIFI Laboratory of Idustrial analysis and Materials Engineering, University 8 May 1945 Guelma, Algaria.
  • Ishak BOUKHETECHE Faculty of sciences and technology, University of Ahmed Draia Adrar, Algeria
  • Ishak LAKSACI Laboratory of Energy, Environment and Systems of Information (LEESI), University Ahmed Draia Adrar, Algeria.
Keywords: Biomaterial, Natural residue, Adsorption, Methylene blue

Abstract

This study aims to assess the use of natural waste (fruit kernels) for the preparation of a bimaterial in order to use it as a natural support for the elimination of a dye (methylene blue) from aqueous solutions for environmental protection. The biomaterial was characterized physicochemically and the determination of methylene blue concentration was carried out by a UV-Visible spectrophotometer. In order to clarify the adsorption process, experiments in a batch system were carried out to study the effect of operating parameters such as the initial concentration of methylene blue (2-10 mg·L-1), biomaterial (0.1-1 g) and the contact time (10-120 min). To describe the adsorption equilibrium, the experimental data were analyzed by the Langmuir isotherm and the Freundlich isotherm. The equilibrium is perfectly described by the Freundlich model (R2>0.99) and the adsorption process is multilayer. The results of the present study suggest that washingtonia seed (WS) can be advantageously used as a low-cost biosorbent for water discoloration

References

[1] F. Sakr, et al., "Analysis and Adsorption study of Methylene Blue on biomaterial using cactus," J. Mater. Environ. Sci., vol. 6(2), pp. 397-406, 2015.
[2] E. Forgacs, et al., "Removal of synthetic dyes from wastewaters: a review," Environ. Int., vol. 30, pp. 953-971, 2004.
[3] K. V. Kumar and K. Porkodi, "Mass transfer,kinetic and equilibrium studies for the biosorption of methylene blue using Paspalum notatum," J. Hazard. Mater., vol. 146, pp. 214-226, 2007.
[4] F. Silva, et al., "Biosorption of methylene blue dye using natural biosorbents made from Weeds," Materials, vol.12(15), pp. 2486-2503, 2019.
[5] E.-K. Guechi and O. Hamdaoui," Biosorption of methylene blue from aqueous solutions by potato (Solanum tuberosum) peel: equilibrium modeling, kinetic and thermodynamic studies, " Desalin. Water Treat., vol. 57(22), pp. 10270-10285, 2016.
[6] O. Khelifi, et al., "Nickel (II) Adsorption from aqueous solutions by physico-chemically modified sewage sludge," Iranian J. Chem. Chem. Eng., vol. 37, pp. 73-87, 2018.
[7] O.Khelifi, et al., "Biosorption of Nickel(II) ions from aqueous solutions by using Chicken eggshells as low-cost biosorbent," Algerian J. of Environ. Sci. Techn., vol. 2:1, pp. 12-16, 2016.
[8] O.Khelifi, et al., "Etude de l’adsorption du Bleu de Methylene (BM) à partir des solutions aqueuses sur un biosorbant préparé a partir des noyaux de datte Algérienne," LARHYSS J., vol. 4(28), pp. 135-148, 2016.
[9] O.Khelifi, et al., "Methyl orange adsorption on biosorbent derived from mango seed kernels," LARHYSS J., vol. 36, pp. 145-156, 2018.
[10] K.S. Low, et al., "Metal adsorption enhancement of rice hull through chemical modification," Environmental Technology, vol. 21, pp. 1239-1244, 2001.
[11] N. Meunier, et al., "Cocoa shells for heavy metal removal from acidic solutions," Bioressource Technology, vol. 90, pp. 255-263, 2003.
[12] A. Annadurai, et al., "Adsorption of heavy metals from water using banana and orange peels," Water Science & Technology, vol. 47, pp. 185-190, 2002.
[13] V.C. Srivastava, et al., "Equilibrium Modeling of Single and Binary Adsorption of Cadmium and Nickel onto Bagasse Fly Ash," Chem. Eng. J., vol. 117, pp. 79-91, 2006.
[14] K.K. Krishnani, et al., "Biosorption mechanism of nine different heavy metals onto biomatrix from rice husk," J. Hazard. Mater., vol. 153, pp. 1222-1234, 2008.
[15] O.Khelifi and I. Mehrez," Equilibrium, kinetics and thermodynamics studies of Methylene blue adsorption from aqueous solutions by biosorbent derived from Algerian date stones," Journal of Water Sciences & Environment Technologies, vol. 2(01), pp. 32-38, 2016.
[16] E.-K. Guechi and O. Hamdaoui, " Sorption of malachite green from aqueous solution by potato peel: Kinetics
and equilibrium modeling using non-linear analysis method," Arab. J. Chem., vol. 9, pp. 414-426, 2011.
[17] I. Langmuir," The constitution and fundamental properties of solids and liquids," J. Am. Chem. Soc., vol. 38, pp. 2221-2295, 1916.
[18] H.M.F. Freundlich," Über die adsorption in lösungen," J. Phys. Chem., vol. 57, pp. 385-470, 1906.
Published
2020-06-15
How to Cite
LANSARIF., EDJEKOUANEM., KHELIFIO., BOUKHETECHEI., & LAKSACII. (2020). Elimination of Methylene Blue by low-cost Biomaterial prepared from Local Natural Residue . Algerian Journal of Renewable Energy and Sustainable Development, 2(01), 60-66. https://doi.org/10.46657/ajresd.2020.2.1.9
Section
Articles

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